DU PONT -- N,N-DIMETHYLANILINE  -- 6810-00N047919
<pre>=====================  Product Identification  =====================

Product ID:N,N-DIMETHYLANILINE
MSDS Date:08/29/1990
FSC:6810
NIIN:00N047919
=== Responsible Party ===
Company Name:DU PONT
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:25827
=== Contractor Identification ===
Company Name:DU PONT
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-9442
CAGE:25827
Company Name:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 13:CONTAM AREA OF BODY INCL SCALP & NAILS IS OF UTMOST
    IMPORTANCE. IF CYANOSIS IS SEV, IV INJECTION OF (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:METHYLENE BLUE, 1 MG/KG OF BODY WT, MAY BE OF VALUE.
    CYANOCOBALAMIN(VITAMIN B-12), 1 MG/ INTRAMUSCULARLY,(ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:WILL SPEED RECOVERY. IV FLUIDS & BLOOD TRANSFUSIONS
    MAY BE INDICATED IN VERY SEVERE EXPOSURES.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:METAL CNTNR FOR DISPOSAL. FLUSH AREA W/PLENTY OF
    DETERGENT & WATER. COMPLY W/FEDERAL, STATE & LOCAL (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:REGULATIONS ON REPORTING RELEASES. AQUATIC TOXICITY:
    96-HR LC50, FATHEAD MINNOWS, 65.6 MG/L.
RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP:RESISTANT WORK CLTHG IF HNDLG MATL ABOVE
    ITS FLASH POINT. IF CONT W/LIQ/VAP CANNOT BE AVOIDED, (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:WEAR A CHEMICAL-PROOF SUIT W/HOOD.
RTECS #:9999999ZZ

Ingred Name:EYE PROT: FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
Other REC Limits:NONE RECOMMENDED

Ingred Name:ANILINE, N,N-DIMETHYL-; (N,N-DIMETHYL-ANILINE)  (SARA III)
CAS:121-69-7
RTECS #:BX4725000
Fraction by Wt: 99%
OSHA PEL:5 PPM;10 PPM STEL, S
ACGIH TLV:5 PPM;10 PPM STEL, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:SUPDAT:NERV SYS DEPRESS W/ANESTH EFTS SUCH AS DIZZ, HDCH,
    CONFUSN, INCOORD & LOSS OF CONSCIOUSNESS. RPTD EXPOS (ING 3)
RTECS #:9999999ZZ

Ingred Name:ING 2:MAY CAUSE RED BLOOD CELL DESTRUCT/ABNORM BLOOD
    FORMING SYS FUNC W/ANEMIA. ANIMAL DATA:ONE, 4-HR EXPOS TO (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3:1900 MG/M3 WAS FATAL TO 2 OF 10 ANIMALS; SURVIVORS
    LOST WT & SHOWED TEMPORARY EYE & NOSE IRRIT. BY INGEST, (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:EFTS IN ANIMALS FROM RPTD DOSES INCL
    METHEMOGLOBINEMIA, CYANOSIS, LETHARGY, TREMORS & EFTS ON BLOOD
    FORMING(ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:ORGANS. LONG-TERM INGEST EXPOS CAUSED MICROSCOPIC
    CHANGES IN SPLEEN. LIFELONG EXPOS TO CMPD INCR NUMBER OF (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:SPLEEN TUMORS IN MALE RATS & STOM TUMORS IN FEMALE
    MICE. THESE RSLTS WERE CLASSIFIED BY NTP AS "SOME EVID" (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:OF CARCIN IN MALE RATS & "EQUIVOCAL EVID" OF CARCIN
    IN FEMALE MICE. CMPD DID PRDCE GENETIC DMG IN MAMMALIAN(ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:CELL CULTURES, BUT HAS NOT BEEN TESTED IN ANIMALS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:UNCON PERS. CALL MD. NOTES TO MD:ABSORP OF
    THIS PROD INTO BODY LEADS TO FORMS OF METHEMOGLOBIN (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:WHICH, IN SUFFICIENT CONC, CAUSES CYANOSIS. IN CASE
    OF SKIN ABSORPTION, SYMPS MAY BE DELAYED. SINCE (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:REVERSION OF METHEMOGLOBIN TO HEMOGLOBIN OCCURS
    SPONT AFTER TERMINATION OF EXPOS, MOD DEGREES OF CYANOSIS(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:NEED TO BE TREATED ONLY BY SUPPORTIVE MEASURES SUCH
    AS BED REST & OXYGEN INHAL. THORO CLEANSING OF ENTIRE(ING 14)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1,350 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:CAUSES EYE BURNS & SKIN IRRIT. HARMFUL
    IF INHALED/ABSORBED THRU SKIN; REDUCES BLOOD'S OXYGEN CARRYING
    CAPACITY. SYMPS MAY BE DELAYED. HUMAN HLTH EFTS OF OVEREXP BY EYE
    CONT MAY INITIALLY INCL IRRIT W/ DISCOMFORT, TEARING/BLURRING OF
    VISION.HIGHER EXPOS MAY CAUSE CORR W/CORNEAL/CONJ ULCERATION. BY
    SKIN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CONT, EFTS MAY INCL IRRIT
    W/DISCOMFORT/RASH. EVID SUGGESTS THAT PERMEATION CAN OCCUR IN AMTS
    CAPABLE OF PRDCG SYSTEMIC TOX. BY INHAL, INGEST/SKIN CONT, EFTS MAY
    INCL METHEMOGLOBINEMIA (REDUCT ION OF BLOOD'S OXYGEN CARRYING
    CAPACITY) W/HDCH, WEAK/CYANOSIS (BLUISH DISCOLORATION OF SKIN),
    POSS PROGRESSING (SUPDAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASES
    OF BONE MARROW OR BLOOD FORMING SYSTEM MAY HAVE INCREASED
    SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES.

=======================  First Aid Measures  =======================

First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. CALL
    MD. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE
    REMOVING CONTAM CLTHG & SHOES. CALL MD. WASH CLTHG BEFORE REUSE &
    DESTROY CO NTAM SHOES. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG,
    GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD.
    INGEST:GIVE 2 GLASSES OF WATER & INDUCE VOMIT. NEVER GIVE ANYTHING
    BY MOUTH TO AN (ING 10)

=====================  Fire Fighting Measures  =====================

Flash Point Method:SCC
Flash Point:145F,63C
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:SMALL FIRES:DRY CHEMICAL, CARBON DIOXIDE (CO*2).
    LARGE FIRES:WATER SPRAY, FOG OR FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
    ISOLATE HAZ & EVACUATE CONFINED AREAS. STAY UPWIND & AVOID SMOKE &
    FUMES. USE WATER SPRAY TO COOL (SUPDAT)
Unusual Fire/Explosion Hazard:OSHA CLASS III A COMBUSTIBLE LIQUID.
    FOLLOW APPROPRIATE NFPA CODES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REVIEW FIRE & EXPLO HAZS & SFTY PRECS BEFORE
    PROCEEDING W/CLEAN UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN
    UP. EVACUATE AREA & KEEP UPWIND OF SPILL. CNTN SPILL W/SAND/EARTH
    DAM, SOAK UP W/SAND/OT HER NONCOMBUST MATL & TRANSFER TO COVERED
    (ING 17)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED AREA
    AWAY FROM HEAT, SPKS & FLAME. DO NOT STORE W/OXIDIZERS OR STRONG
    ACIDS. KEEP CNTNR TIGHTLY CLSD.
Other Precautions:HANDLE IN A MANNER TO PVNT HUMAN CONT. DO NOT GET IN
    EYES, ON SKIN/ON CLTHG. AVOID BRTHG VAP. COMBUSTIBLE LIQUID! CAUSES
    EYE BURNS! CAUSE SKIN IRRITATION. HARMFUL IF INHALED/ABSORBED THRU
    SKIN.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF CONTACT W/LIQUID OR VAPOR CANNOT BE AVOIDED,
    WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE PROVIDED TO KEEP VAPOR
    CONCENTRATIONS BELOW THE RECOMMENDED EXPOSURE LIMIT.
Protective Gloves:BUTYL RUBBER GAUNTLET GLOVES.
Eye Protection:ANSI APPVD CHEM SPLASH GOGGS (ING 21)
Other Protective Equipment:ANSI APVD EMER EYEWSH & DELUGE SHWR . HV
    AVAIL & WEAR AS APPROP TO PVNT LIQ/VAP EXPOS:FTWEAR &
    APRON,FLAME-(ING 19
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:5.4(WATER EXTRACT). FIRE FIGHT PROC:CNTNRS & REDUCE VAPS. FIGHT FIRE
    FROM MAX DIST. RUN-OFF FROM FIRE CONTROL MAY CAUSE POLLUTION. HAZ
    DECOMP PROD:LOWER THIS EXOTHERMIC DECOMP TEMP. EFTS OF OVEREXP :TO
    DIZZ, INCOORD, SHORTNESS OF BREATH,INCR PULSE RATE & LOSS OF
    CONSCIOUSNESS. HIGHER EXPOS MAY CAUSE TEMPORARY(ING 2)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:379F,193C
Melt/Freeze Pt:M.P/F.P Text:36.0F,2.2C
Decomp Temp:Decomp Text:752F,400C
Vapor Pres:0.75 @ 25C
Vapor Density:4.2
Spec Gravity:0.956
pH:SUPDAT
Evaporation Rate &amp; Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:0.18 WT% @ 20C
Appearance and Odor:LIGHT YELLOW (STRAW COLOR)-DARKENS IN STORAGE, OILY
    LIQUID; AROMATIC AMINE ODOR

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZERS & STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WILL OCCUR AT TEMPS >400C (752F)
    RELEASING HAZ NITROGEN OXIDE GAS. CONTAM BY FOREIGN MATLS/ACIDIC
    CNDTNS MAY (SUPP DATA)

====================  Disposal Considerations  ====================

Waste Disposal Methods:COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS. IF
    APPROVED, MAY BE INCINERATED OR SENT TO AN APPROVED HAZARDOUS
    MATERIAL DISPOSAL AREA.

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